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Synthesis and characterization of green phenolic resin with olive oil mill wastewater
Environmental Sciences Europe volume 35, Article number: 10 (2023)
Olive oil mill wastewater (OMW), a by-product of the olive oil industry, each year is generated millions of tons all over Mediterranean countries. Uncontrolled disposal of the OMW leads to massive environmental problems including soil and water pollution. In this experimental study, the OMW was used to partly replace clean water for getting prepared formaldehyde solution. Then, phenol and formaldehyde solutions were synthesized under alkali conditions to obtain more green phenol–formaldehyde (PF) resin. The effect of the OMW substitution level on the chemical and thermal properties of PF resin was examined by the Fourier transform infrared (FT-IR) spectral and thermogravimetric (TGA) analysis, respectively. Moreover, the bonding strength of each PF resin was evaluated under dry and wet conditions. It was found that FT-IR measurements showed that the PF resin containing various amounts of the OMW had a chemical structure very similar to the PF resin. The thermogravimetric analysis demonstrated that the low‐molecular‐weight organics in the OMW had negatively affected the thermal stability of the modified PF resins. In addition, the wood samples bonded with the PF resin containing up to 30 wt% OMW met the minimum requirements of interior and exterior bonding performance according to standard EN 12765. The OMW could be replaced by clean water up to 30 wt% for the production of green phenolic resin.
Olive oil production, which is common throughout the Mediterranean countries, plays an essential role in the social, economic and environmental in producing countries. Olive oil mill wastewater (OMW) is composed of olive fruit extract water and water added into the olive oil production process, which is the main waste product of the olive oil industry. The OMW is a dark, acidy, and free-flowing liquid with foul-smelling. It is consisting of water (83–92%), organic compounds, including 2-Hydroxyphenol, 4-Methyl-1,2-benzenediol, Hydroxy-tyrosol, 2-Phenylethanol, etc.) (4–16%) and minerals (1–2%). Uncontrolled disposal of the OMW leads to massive environmental problem including soil and water pollution. Environmental research has shown a strong interest in finding ways to reduce this waste. Numerous treatment techniques, including thermal, chemical, biological, and physicochemical ones, have been found to control OMW in earlier investigations. However, additional research is still required to identify easy, sustainable, and cost-effective solutions [1,2,3,4,5,6,7,8,9,10].
Phenolic resins are fundamentally classified into two categories: alkaline-catalyzed resols and acid-catalyzed novolacs. Conventionally, PF resol is a thermosetting resin derived from the addition and condensation reactions of phenol and paraformaldehyde under alkalinity conditions. Before use, paraformaldehyde is dissolved in water at 90 °C to form a formaldehyde solution of about 36–37 wt%. PF resol resins are generally used as an adhesive to produce wood-based products including particle boards, laminated boards and more, due to their high water resistance, excellent mechanical strength, outdoor durability and less volatile organic compound emissions [11, 12], [13,14,15,16].
There are many reported studies on the production of more green PF resin. Generally, they are related to the replacement of phenol by renewable resources such as bio-oil [17, 18], Kokten et al., 2018; , lignin products [21,22,23,24,25,26,27] and other natural materials [28,29,30,31].
In this study, the OMW was used to partly substitute clean water for getting ready formaldehyde solution. Then, phenol and formaldehyde solution were synthesized under alkali conditions to obtain green PF resin. The effect of the OMW substitution level on the chemical and thermal properties of the PF resin was examined by the Fourier transform infrared (FT-IR) spectral and thermogravimetry (TGA) analysis, respectively. Moreover, the bonding strength of each PF resin was evaluated by EN 205 standard and compared with the values specified in the EN 12765 standard.
Olive oil mill wastewater (OMW) was collected from a local plant of olive oil in Balıkesir city, West of Turkey. It was stored at − 18 °C until use (pH 4.8; organic matter content: 7.4%). The OMW was filtered through a mesh size of 100 μm using filter paper before preparing the formaldehyde solution. The sodium hydroxide pellets were of analytical grade (NaOH, Sigma-Aldrich). Phenol (90% purity) and paraformaldehyde (98% purity) were supplied from the Gentaş Chemical Industry and Trade Marketing Inc. in Izmit city, Turkey.
Synthesis of the resin
Before the synthesis of the PF resin, a formaldehyde solution (at a concentration of 37 wt%) with different OMW/clean water substitute rates (0, 10, 20, 30, and 40 wt%) was prepared, the experimental design is given in Table 1. In a typical synthesis, the PF solution was put in the reactor, and then 0.70 of the whole NaOH solution (50 wt%) was unhurriedly incorporated at the temperature of 60 °C. The solution was warmed up to 90 °C, and it was held at a temperature of 90 °C continuously with stirring for 60 min. Then, it was cooled down to a temperature of 60 °C. Since PF resin is cured during the hot-pressing process at high pH levels, the other part of NaOH (0.30 of total weight solution) was loaded to adjust the pH (about 11.0) into the solution. Finally, at end of the synthesis, the resin was cooled up to a temperature of 25 °C. The details of the resin reactor were extensively described by .
Characterisation of the resin
The values of pH and viscosity of the PF resins were determined with a pH meter (TES-1380) and a digital viscometer (Brookfield, model: Dv-IPrime) at 25 °C, respectively. Free formaldehyde content was measured by the method of hydroxylamine hydrochloride based on European Standard DIN EN ISO 9397. The chemical structure of the PF resins was characterized by an Alpha FTIR spectrometer in the range of 400–4000 cm−1. The thermal behaviour of the PF resins was performed using a TG analyzer (HITACHI STA 7300) at temperatures range of 20–700 °C and the heating rates of 10 °C/min under a nitrogen atmosphere.
The PF resins were further evaluated as adhesives in wood lamellas samples. Beech wood (Fagus orientalis Lipsky) planks were used to investigate the bonding quality of the PF resins in accordance with standard EN 205. Beech wood samples were cut into dimensions of 20 × 50 × 100 mm and were bonded with various types of PF resin. The PF resin was applied to the surface of the lamella at a ratio of about 200 g/m2 by a hand brush. The press conditions such as pressure, temperature and duration were performed at 130 °C and 1.6 MPa for 10 min, respectively. Pressed wood samples were cut into a size of 5 × 10 × 150 mm. Before the bonding test, the treatments of the samples were determined by standard EN 12765. The wood samples from each group of the resin were divided into three subgroups for the different treatments. The treatments are summarized in Table 2.
Results and discussion
Characterization of the PF resins
The pH, viscosity values and free-formaldehyde content of all the PF resins are given in Table 3. As shown in this table, when the amount of the OMW increased from 0 to 40 wt%, the pH value of PF resin decreased from 11.90 to 10.67. The OMW contains organics, which are mainly phenolic compounds, and it has a low pH value (4.8). These compounds and the low pH value of the OMW decreased the pH value of the PF resins synthesized with the OMW. All the PF (PF10-PF40) resins synthesized with the OMW exhibited a higher viscosity than the reference PF resin. The free-formaldehyde content of the PF resins increased from 0.12 to 0.38% as the amount of the OMW substitution rate increased from 0 to 40 wt%. These results were not unexpected due to the OMW composed of high phenol and organic acid instead of clean water. These findings were well consistent with previous reports on the basic properties of green PF resins [18, 22, 33,34,35].
The FT-IR spectra of PF, PF10, PF20, PF30 and PF40 resins are illustrated in Fig. 1. It was observed that the replacement of the OMW had no distinctive effect on the resin in terms of the chemical structure. Except for the PF40, the spectrum of the PF40 resin was different from others, and mostly aromatic rings were observed. The characteristic bands at about 1600, 1500, 1250, 1150, 990 and 750 cm–1 could be attributed to the phenolics for the IR spectra of all PF resin. In addition, with the increase in the OMW substitution level the band at about 990 cm–1 became weak, and it vanished finally. FT-IR analysis results were consistent with previous reports prevıous reports on the IR analysis results of the PF resin and green PF resins , Zhang et al., 2013; [35, 38, 39].
The thermal behaviour of the PF and OMW containing the modified PF resins was characterised by TGA analysis (see Fig. 2). Generally, thermal degradation of phenolic resins occurred in three main steps, where the mass loss in the first stage might be caused by the release of free-phenol, formaldehyde, oligomer and water, due to the further cross-linking or condensation reaction between methyl groups (post-curing). The second stage occurred at a temperature between 350 and 450 °C. The huge mass loss in this stage might be due to the decomposition of bridged methylene (thermal reforming). Also, the phenol is further degraded into a carbonaceous structure at about 500–550 °C. The weight loss occurring in the last stage until 600 °C could be attributed to the fracture of the methylene bridge structure at high temperatures [26, 40, 41]: [42, 43]. TGA curves of reference PF resin and PF resins containing different amounts of OMW are shown in Fig. 2. As can be seen in Fig. 2, the weight losses of the PF resins containing different amounts of OMW showed a similar trend and the PF resin had higher thermal stability than that of PF resins containing OMW. The PF resins with a lower content of the OMW (PF10 and PF20) exhibited similar thermal behaviours to the reference PF resin. The weight loss of the PF resins with 30 wt% and 40 wt% OMW replacements dramatically increased at the temperature of 250 °C. This relatively low thermal stability can be explained by the presence of low molecular weight compounds in OMW. These compounds might be led to the decomposing more easily at high temperatures of the PF resins containing different amounts of the OMW.
Bonding performance of the PF resins
The data of the bonding strength of PF and PF with OMW resins are given in Table 4. The bonding strength of the wood samples bonded with the reference resin was higher than that of the samples bonded with the PF resins containing 10–40 wt% of the OMW. As the OMW substitution rate reached up to 40 wt%, the strength was dramatically decreased under dry conditions. However, the specimens bonded with PF resins containing OMW with 10 wt%, 20 wt%, and 30 wt% comply with met the minimum requirements, which was the durability class C1(≥ 10) according to standard EN 12765 under dry conditions. The highest bonding strength with a value of 8.8 N/mm2 was found in the reference resin specimens, followed by PF10 resin (8.2 N/mm2) under wet conditions (pre-treatment 2). For pre-treatment 3, a similar trend was observed with treatment 2. The bonding strength decreased dramatically after pre-treatment 3, as matched with pre-treatment 1 and pre-treatment 2. The bond quality was negatively affected by the presence of the OMW more or less. When the amount of the OMW in the PF resin was increased up to 30 wt%, the bonding strength of the samples decreased from 6.1 to 2.9 N/mm2. However, the samples bonded with the PF, PF10, PF20 and PF30 exceeded the minimum requirements for class C3 specified in EN 12765 standard. According to the bonding test results, it was recommended that the OMW can be partially replaced by clean water for the production of the green PF resin.
In this study, the OMW with a rich phenol content was used as the raw material to substitute clean water partially. It was synthesized with phenol and formaldehyde to produce green PF resin (Additional file 1). The effect of the OMW substitution level on the chemical and thermal properties of the PF resin was investigated by FT-IR spectral and thermogravimetric analysis respectively. Also, the bonding performance of each PF resin was evaluated by bonding tests. Based on the findings, the following conclusions can be asserted:
The basic properties, such as pH value, viscosity, and free formaldehyde content of the PF resins, were affected by the incorporation of the OMW. With the addition of OMW, the pH value of PF resins exhibited a decreasing trend to some extent. In contrast, the viscosity value and free formaldehyde content of the PF resin showed an increasing trend.
FT-IR spectra showed that the green PF resin could be successfully produced by polymerization of the OMW, phenol and formaldehyde.
The thermal stability of the reference resin was higher than PF30 and PF40 resins when the temperature was higher than 250 °C. The low‐molecular‐weight organics in the OMW negatively affected the thermal stability of the green PF resin.
Further increment in the OMW content decreased the bonding strength of the wood samples under dry conditions. Furthermore, regarding the bonding strength after pre-treatment 2 and 3 tests, the samples bonded with PF resins containing the OMW showed a lower bonding performance compared with bonded with reference PF resin. However, the PF resins containing the OMW, except for PF 40 resin, were satisfied the minimum requirements for durability classes of 1, 2, and 3 specified in EN 12765. Based on the findings of the present study, it was concluded that the OMW could be partially substituted (up to 30 wt%) to produce green phenolic resins for wood composites.
Availability of data and materials
The data used and analyzed during the current study are available from the corresponding author on reasonable request.
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The authors would like to thank the central laboratory staff of Aksaray University.
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Özbay, G., Ayrilmis, N. & Ahmad, M.S. Synthesis and characterization of green phenolic resin with olive oil mill wastewater. Environ Sci Eur 35, 10 (2023). https://doi.org/10.1186/s12302-023-00719-2
- Green PF resin
- Olive oil mill wastewater (OMW)
- TGA analysis