Non-target screening of organic pollutants and target analysis of halogenated polycyclic aromatic hydrocarbons in the atmosphere around metallurgical plants by high-resolution GC/Q-TOF-MS

Yang, Lili; Wu, Jiajia; Zheng, Minghui; Cao, Zhe; Li, Cui; Shi, Miwei; Liu, Guorui

doi:10.1186/s12302-020-00376-9

Environmental Sciences Europe

Table 2 Quantitative method performance for chlorinated and brominated polycyclic aromatic hydrocarbons

From: Non-target screening of organic pollutants and target analysis of halogenated polycyclic aromatic hydrocarbons in the atmosphere around metallurgical plants by high-resolution GC/Q-TOF-MS

Compound name	Retention time/min	Quantitative ion	Qualitative ion	Internal standard (ISTD)	LOQ/pg/μL
Polychlorinated naphthene (Nap)
2-Cl-Nap	11.66	162.0231	164.0202	ISTD 1	3.0
1,5-diCl-Nap	15.96	195.9841	197.9812	ISTD 1	3.5
1,2,3-TriCl-Nap	22.38	229.9451	231.9422	ISTD 1	2.6
1,2,3,5-TetraCl-Nap	27.81	265.9033	263.9062	ISTD 2	2.1
1,2,3,5,7-PentaCl-Nap	32.47	299.8643	301.8614	ISTD 3	2.4
1,2,3,4,6,7-HexaCl-Nap	39.94	333.8253	335.8224	ISTD 4	2.7
1,2,3,4,5,6,7-HeptaCl-Nap	47.91	367.7863	365.7892	ISTD 5	3.5
OctaCl-Nap	52.92	403.7444	401.7473	ISTD 6	5.0
ISTD 1_1,3,5,7-TetraCl-Nap-¹³C	24.92	275.9368	273.9397
ISTD 2_1,2,3,4-TetraCl-Nap-¹³C	28.39	275.9368	273.9397
ISTD 3_1,2,3,5,7-PentaCl-Nap-¹³C	32.45	309.8978	311.8948
ISTD 4_1,2,3,5,6,7-HexaCl-Nap-¹³C	39.98	343.8588	345.8559
ISTD 5_1,2,3,4,5,6,7-HeptaCl-Nap-¹³C	47.90	377.8199	379.8169
ISTD 6_OctaCl-Nap-¹³C	52.92	413.7779	411.7809
5-Bromoacenapthene	23.54	231.9882	233.9862	ISTD 7	2.1
2-Bromofluorene	26.74	243.9882	245.9862	ISTD 7	2.9
3-Chlorophenanthrene	29.29	212.0389	214.0358	ISTD 7	1.6
2/9-Chlorophenanthrene	29.59	212.0389	214.0358	ISTD 7	1.0
1-Chloroanthracene	29.59	212.0389	214.0358	ISTD 8	1.5
2-Chloroanthracene	30.01	212.0389	214.0358	ISTD 8	3.3
2,7-2 Chlorofluorene	30.62	233.9998	235.9968	ISTD 8	2.3
1,2-Dibromoacenaphthylene	30.70	309.8811	307.8831	ISTD 8	4.2
3-Bromophenanthrene	33.06	257.9867	255.9883	ISTD 9	2.7
9-Bromophenanthrene	33.47	257.9867	255.9883	ISTD 9	3.3
2-Bromophenanthrene	33.47	257.9867	255.9883	ISTD 9	4.7
1-Bromoanthracene	33.70	257.9867	255.9883	ISTD 9	3.8
9-Bromoanthracene	34.02	257.9867	255.9883	ISTD 9	3.9
1,4-Dichloroanthracene	36.08	245.9998	247.9968	ISTD 9	1.5
1,5/9,10-Dichloroanthracene	36.59	245.9998	247.9968	ISTD 9	2.6
9,10-Dichlorophenanthrene	37.07	245.9998	247.9968	ISTD 9	2.8
2,7-Dibromofluorene	38.37	323.8967	325.8947	ISTD 9	2.9
3-Bromofluoranthene	42.99	279.9883	281.9862	ISTD 10	2.7
1,8/1,5-Dibromoanthracene	43.94	335.8967	337.8947	ISTD 10	3.6
9,10-Dibromoanthracene	44.31	335.8967	337.8947	ISTD 10	3.2
4-Bromopyrene	44.80	279.9883	281.9862	ISTD 10	3.9
9,10-Dibromophenanthrene	44.87	335.8967	337.8947	ISTD 10	2.9
1-Bromopyrene	45.02	279.9883	281.9862	ISTD 10	2.3
3,8-Dichlorofluoranthene	46.03	269.9998	271.9969	ISTD 10	4.5
1,5,9,10-Tetrachloroanthracene	51.35	315.9189	313.9218	ISTD 11	4.5
2-Bromotriphenylene	52.81	306.0039	308.0019	ISTD 12	4.0
1,6-Dibromopyrene	53.21	359.8967	361.8947	ISTD 12	4.5
6-Chlorobenzo[a]pyrene	59.39	286.0544	288.0515	ISTD 12	7.2
ISTD 7_9-Chlorophenanthrene-¹³C	29.56	218.0589	220.0559
ISTD 8_2-Chloroanthracene-¹³C	30.01	218.0589	220.0559
ISTD 9_9-Bromophenanthrene-D₉	33.20	265.0447	267.0427
ISTD 10_1-Chloropyrene-¹³C	41.16	242.0589	244.0559
ISTD 11_7-Chlorobenz[a]anthracene-¹³C	50.63	268.0745	270.0716
ISTD 12_7-Bromobenz[a]anthracene-¹³C	53.23	312.0240	314.0220

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