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Table 2 Summary of the percentage of freshwater monitoring samples complying with the proposed EQS values for diclofenac in freshwater derived in this study (0.23 µg/L) and by EC [14] (0.0054 µg/L)

From: Environmental quality standards for diclofenac derived under the European water framework directive: 2. Avian secondary poisoning

Data set

Population density (people/sq. km of land area)a

Number of samples

Sample density (samples/people/sq. km of land area)

Percentage of samples < 0.0054 μg/L

Percentage of samples < 0.230 μg/L

Hungary

106.84

20

0.19

25.0

70.0

Germany

238.25

233

0.98

5.2

74.2

Cyprus

130.67

4

0.03

25.0

75.0

Flanders

N.C

1025

N.C

0.2

78.0

Austria

108.06

18

0.17

0.0

83.3

Luxembourg

260.20

8

0.03

25.0

87.5

Denmark

145.79

8

0.05

37.5

87.5

Portugal

112.50

218

1.94

0.0

90.8

Poland

123.95

180

1.45

5.0

91.1

Italy

200.03

50

0.25

36.0

94.0

Netherlands

518.00

603

1.16

21.2

94.4

Slovenia

104.30

30

0.29

0.0

96.7

England

433.96

576

1.33

0.0

96.9

France

123.08

21,472

174.46

41.7

98.2

Danube

N.C

266

N.C

26.7

98.9

Sweden

25.42

93

3.66

88.2

98.9

Rhine

N.C

816

N.C

23.3

99.5

Northern Ireland

137.43

284

2.07

0.0

100.0

Slovakia

113.54

12

0.11

0.0

100.0

Switzerland

218.57

714

3.27

0.0

100.0

Estonia

30.62

9

0.29

22.2

100.0

Scotland

70.17

14

0.20

35.7

100.0

Finland

18.20

46

2.53

37.0

100.0

Ireland

72.50

8

0.11

37.5

100.0

Croatia

71.52

6

0.08

50.0

100.0

Wales

152.85

4

0.03

50.0

100.0

Iceland

3.63

3

0.83

66.7

100.0

Latvia

30.63

11

0.36

90.9

100.0

Lithuania

44.62

11

0.25

100.0

100.0

Malta

1641.52

2

1.22E-03

100.0

100.0

  1. aPopulation density for 2020; all data from The World Bank [57] except for United Kingdom constituent countries which were obtained from the Office of National Statistics [46]
  2. N.C. not calculable