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Table 2 Concentrations (µg kg−1 wet weight) of flame retardants in blue mussels and eelpout filet in 2015 and long-term trends

From: Chemicals of emerging concern in marine specimens of the German Environmental Specimen Bank

Chemical

Blue mussel soft body

Eelpout filet

NS 1

NS 2

BS

NS 1

NS 2

BS

Conc. (µg kg−1)

Trend

Conc. (µg kg−1)

Conc. (µg kg−1)

Trend

Conc. (µg kg−1)

Conc. (µg kg−1)

Conc. (µg kg−1)

DP

0.0073

o

0.0083

< LOQa

–

0.0029

< LOQa

< LOQa

Dec 602

0.0048

–

0.0033

0.001

–

0.0107

0.0048

0.0009

Dec 603

0.001

–

0.0006

< 0.0003

 

0.0018

0.0005

< 0.0003

Dec 604

< 0.0004

 

< 0.0005

< 0.0005

 

< 0.0005

< 0.0005

< 0.0004

Cl10-antiDP

< 0.0002

 

< 0.0002

< 0.0002

 

< 0.0002

< 0.0002

< 0.0002

Cl11-antiDP

0.0001

–

0.0001

< 0.0001

 

< 0.0002

<0.0001

< 0.0001

1,5-DPMA

< 0.0001

 

< 0.0002

< 0.0001

 

< 0.0002

< 0.0001

< 0.0002

EH-TBB

< 0.0111

 

< 0.0125

< 0.0143

 

< 0.0126

< 0.0126

< 0.0117

BEH-TEBP

< 0.0384

 

0.0559

0.0506

 

0.0728

< 0.0514

< 0.0404

PBEB

< 0.0003

 

< 0.0003

< 0.0003

 

< 0.0003

< 0.0003

< 0.0003

PBT

0.004

+

0.0053

0.0067

o

0.0081

0.0072

0.013

TBP-AE

< 0.0043

 

< 0.0049

< 0.0056

 

< 0.0049

< 0.0049

< 0.0046

BATE

< 0.0014

 

< 0.0016

< 0.0018

 

< 0.0016

< 0.0016

< 0.0015

TBP-DBPE

< 0.0269

–

0.0989

< 0.0345

–

< 0.0306

< 0.0306

0.103

BTBPE

< 0.0083

 

< 0.0093

< 0.0106

 

< 0.0094

< 0.0094

< 0.0087

DBDPE

< 0.0751

 

0.109

< 0.0964

 

< 0.0854

< 0.0855

< 0.0789

HBBz

< 0.0008

 

< 0.0009

< 0.0011

o

< 0.0009

< 0.001

< 0.001

TBA

< 0.0142

o

< 0.016

0.0239

o

0.0219

< 0.0161

0.0694

∑ 6 PBDE

0.0208

–

0.363

0.0455

o

0.0762

0.0288

0.0371

  1. Sampling sites: NS 1: North Sea—Lower Saxony Wadden Sea; NS 2: North Sea—Schleswig–Holstein Wadden Sea; BS: Baltic Sea—Bodden National Park
  2. Italics: quantified substances; DP: sum of syn-DP and antiDP
  3. Trends: o: no significant linear trend; +: increase; −: decrease; blank: insufficient data, no trend calculation possible. Time intervals for trend calculations: blue mussels: NS 1: 1985–2015 BS: 1992–2015. For NS 2 and for eelpout filet, data were only available for 2015. Trend calculation based on lipid normalized concentrations. For full names of chemicals refer to Table 1
  4. aLOQ for syn-DP: 0.002–0.0026 µg kg−1, LOQ for antiDP: 0.00225–0.0029 µg kg−1, depending on matrix (Additional file 1: Table S1–S6)