Table 1 Substances analyzed in marine samples of the German Environmental Specimen Bank

Flame retardants

 syn-DP^c,d

Dechlorane Plus, syn-isomer

135821-03-3

x

x

x

x

x

x

 antiDP^c,d

Dechlorane Plus, anti-isomer

135821-74-8

x

x

x

x

x

x

 Dec 602

Dechlorane 602

31107-44-5

x

x

x

x

x

x

 Dec 603

Dechlorane 603

13560-92-4

x

x

x

x

x

x

 Dec 604

Dechlorane 604

34571-16-9

x

x

x

x

x

x

 Cl₁₀-antiDP

Decachloropentacyclooctadecadiene

Not available

x

x

x

x

x

x

 Cl₁₁-antiDP

Undecachloropentacyclooctadecadiene

Not available

x

x

x

x

x

x

 1,5-DPMA

1,5-Dechlorane Plus mono-adduct

135821-04-4

x

x

x

x

x

x

 EH-TBB (EHTeBB)

2-Ethylhexyl 2,3,4,5-tetrabromobenzoate

183658-27-7

x

x

x

x

x

x

 BEH-TEBP (TBDEHP; TBPH)

Bis(2-ethylhexyl)-tetrabromophthalate

26040-51-7

x

x

x

x

x

x

 PBEB

2,3,4,5,6-Pentabromoethylbenzene

85-22-3

x

x

x

x

x

x

 PBT

2,3,4,5,6-Pentabromotoluene

87-83-2

x

x

x

x

x

x

 TBP-AE (ATE)

2,4,6-Tribromophenyl allyl ether

3278-89-5

x

x

x

x

x

x

 BATE

2-Bromoallyl 2,4,6-tribromophenyl ether

99717-56-3

x

x

x

x

x

x

 TBP-DBPE (DBPE)

2,4,6-Tribromophenyl-2,3-dibromopropyl ether

35109-60-5

x

x

x

x

x

x

 BTBPE

1,2-bis(2,4,6-tribromophenoxy)ethane

37853-59-1

x

x

x

x

x

x

 DBDPE

Decabromodiphenyl ethane

84852-53-9

x

x

x

x

x

x

 HBBz

1,2,3,4,5,6-Hexabromobenzene

87-82-1

x

x

x

x

x

x

 TBA

2,4,6-Tribromoanisole

607-99-8

x

x

x

x

x

x

 ∑ 6 PBDE

Polybrominated diphenylether

32534-81-9

x

x (2003–2017)

x (2003–2017)

x (2003–2017)

 PFBA

Perfluorobutanoate

375-22-4/2218-54-4

x

x

x

x

x

x

 PFPeA

Perfluoropentanoate

2706-90-3

x

x

x

x

x

 PFHxA

Perfluorohexanoate

307-24-4

x

x

x

x

x

x

x

x

x

 PFHpA

Perfluoroheptanoate

375-85-9

x

x

x

x

x

x

x

x

x

 PFNA^c

Perfluorononanoate

375-95-1

x

x

x

x

x

x

x

x

x

 PFDA^c

Perfluorodecanoate

335-76-2

x

x

x

x

x

x

x

x

x

 PFUnDA^c

Perfluoroundecanoate

2058-94-8

x

x

x

x

x

x

 PFDoDA^c

Perfluorododecanoate

307-55-1

x

x

x

x

x

x

x

x

x

 PFTriDA^c

Perfluorotridecanoate

72629-94-8

x

x

x

x

x

x

 PFTeDA

Perfluorotetradecanoate

373-06-7

x (2015)

x (2015)

 PFBS

Perfluorobutane sulfonate

375-73-5/59933-66-3/45187-15-3

x

x

x (2015)

x

x (2015)

 PFHxS^c

Perfluorohexane sulfonate

355-46-4/108427-53-8

x

x

x

x

x

x

x

x

x

 PFHpS

Perfluoroheptane sulfonate

375-92-8

x

x

x

x

x

x

 PFDS

Perfluorodecane sulfonate

335-77-3/126105-34-8

x

x

x

x

x

x

x

x

x

 PFOSA

Perfluorooctane sulfonamide

754-91-6

x

x

x

x

x (2015)

x

x

x (2015)

 PFOA^c

Perluorooctanoic acid

335-67-1

x

x

x

x

x

x

x

x

x

 PFOS

Perfluorooctane sulfonic acid

1763-23-1

x

x

x

x

x

x

x

x

x

 D4^c

Octamethylcyclotetrasiloxane

556-67-2

x

x

x

 D5^c

Decamethylcyclopentasiloxane

541-02-6

x

x

x

 D6^c

Dodecamethylcyclohexasiloxane

540-97-6

x

x

x