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Anthropogenic platinum fluxes: Quantification of sources and sinks, and outlook

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An Erratum to this article was published on 01 February 2006

Abstract

Employing the data available to date, anthropogenic Pt fluxes are calculated for Germany with special emphasis on the Pt emitted by cars equipped with catalytic converters. Pt fluxes are quantified using five different methods (street deposition, automobile emission rate, sewage sludges, atmospheric load, industrial consumption). During the first and the second methods, approx. 100 kg of emitted Pt are seen to result for both for the mid 1990’s. Up to the year 2018, a total of 2100 kg of Pt will be emitted by cars equipped with catalytic converters. The diffuse atmospheric Pt deposition amounts to 0.73 – 4.4 μg/m2y or 260 kg Pt/year. Industrial sources emitting Pt into the atmosphere are likely but difficult to quantify. The enrichment of Pt in soils during agriculture fertilization with sewage sludges and during diffuse atmospheric deposition result in a level of 46 – 460 ng/kg up to the year 2018. Although this is slightly below the geogenic background, a comparison with the pollution history of Pb implies that forthcoming environmental Pt enrichment should not be neglected.

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References

  • Alt, F.;A. Bambauer, K. Hoppstock, B. Mergler, G. Tölg (1993): Pt traces in airborne particulate matter — determination of whole content, particle size distribution and soluble Pt. Fres. J. Anal. Chem. 346, 693–696

    Article  CAS  Google Scholar 

  • Alt, F.;H.R. Eschnauer, B. Mergler, J. Messerschmidt, G. Tölg (1997): A contribution to the ecology and enology of platinum. Fres. J. Anal. Chem. 357, 1013–1019

    Article  CAS  Google Scholar 

  • Beck, G.;H.-H. Beyer, W. Gerhartz, J. Haußelt, U. Zimmer (1995): Edelmetalltaschenbuch (Ed.:Degussa AG), Hüthig publ., Heidelberg, 676 pp.

    Google Scholar 

  • Bliefert, C. (1994): Umweltchemie. VCH publ., Weinheim, 452 pp.

    Google Scholar 

  • Buat-Ménard, P. (1983): Particle Geochemistry in the atmosphere and oceans. In: Air-Sea Exchange of Gases and Particles (Ed.P.S. Liss andW.G.N. Slinn), Reidel Publ, Dordrecht, 455–533

    Google Scholar 

  • Cubelic, M.;R. Pecoroni, J. Schäfer, J.-D. Eckhardt, Z. Berner, D. Stuben (1997): Verteilung verkehrsbedingter Edelmetallemissionen in Böden. UWSF — Z. Umweltchem. Ökotox. 9 (5), 249–258

    Article  CAS  Google Scholar 

  • Drasch, G.A. (1982): Lead burden in prehistorical, historical and modern human bones. Sci. Tot. Environ. 24, 199–231

    Article  CAS  Google Scholar 

  • Duce, R.A, et al. [22 authors) (1991): The atmospheric input of trace species to the world ocean. Global biogeochem. cycles 5 (3), 193–259

    Article  CAS  Google Scholar 

  • EU (1995): Assessment of potential risks to the environment posed by medical products for human use (excluding products containing alive genetically modified organisms). Direction General III, No. 5504/94 Draft 6, version 4, Brussels, January 5

    Google Scholar 

  • Ewers, U.;H.-W. Schlipköter (1991): Lead. In: Metals and their compounds in the environment (Ed.E. Merian), VCH publ., Weinheim, 971–1014

    Google Scholar 

  • Goldberg, E.D.;M. Koide (1990): Understanding the marine chemistries of the Pt group metals. Mar. Chem. 30, 249–257

    Article  CAS  Google Scholar 

  • Grupe, G. (1991): Anthropogene Schwermetallkonzentrationen in menschlichen Skelettfunden. UWSF — Z. Umweltchem. Ökotox. 3 (4), 226–229

    Article  Google Scholar 

  • Hees, T.;B. Wenclawiak, S. Lustig, P. Schramel, M. Schwarzer, M. Schuster, D. Verstraete, R. Dams, E. Helmers (1998): Distribution of PGE (Pt, Pd, Rh) in environmental and clinical matrices: composition, analytical techniques and scientific outlook (status report). ESPR — Environ. Sci. Poll. Res. 5 (2), 105–111

    Article  CAS  Google Scholar 

  • Helmers, E.;L. Mart, M. Schulz-Baldes, W. Ernst (1990): Temporal and spatial variations of lead concentrations in Atlantic surface waters. Mar. Poll. Bull. 21 (11), 515–518

    Article  CAS  Google Scholar 

  • Helmers E.;N. Mergel, R. Barchet (1994): Pt in Klärschlammasche und an Gräsern. UWSF-Z. Umweltchem. Ökotox. 6 (3), 130–134

    Article  CAS  Google Scholar 

  • Helmers, E.;G. Wilk, K. Wippler (1995): Pb in the urban environment — studying the strong decline in the environment. Chemosphere 30 (1), 89–101

    Article  CAS  Google Scholar 

  • Helmers, E. (1997a): Pt emission rate of automobiles with catalytic converters. ESPR — Environ. Sci. Poll. Res. 4 (2), 100–103

    CAS  Google Scholar 

  • Helmers, E. (1997b): Sampling of sea and fresh water for the analysis of trace elements. In: Sampling and Sample Preparation (Ed.M. Stoeppler), Springer, Berlin, 26–42

    Google Scholar 

  • Helmers, E.;M. Schwarzer, M. Schuster (1998): Comparison of Pd and Pt in environmental matrices: Pd pollution by automobile emissions? ESPR — Environ. Sci. Poll. Res. 5 (1), 44–50

    Article  CAS  Google Scholar 

  • Helmers E.;N. Mergel (1998): Pt and Rh in a polluted environment: studying the emissions of automobile catalysts with emphasis on the application of CSV rhodium analysis. Fres. J. Anal. Chem. 362, 522–528

    Article  CAS  Google Scholar 

  • Helmers, E.; K. Wippler (submitted): Elementgehalte von Klärschlammaschen 1972–1994: Trends bei Umwelteinträgen und Klärtechnik. Vom Wasser

  • Hodge, V.F.;M.O. Stallard (1986): Platinum and Palladium in roadside dust. Environ. Sci. Techn. 20(10), 1058–1060

    Article  CAS  Google Scholar 

  • König, H.P.;R.F. Hertel, W. Koch, G. Rosner (1992): Determination of Pt emissions from a three-way catalyst-equipped gasoline engine. Atmos. Environ. 26A (5), 741–745

    Google Scholar 

  • Kriews, M. (1992): Charakterisierung mariner Aerosole in der Deutschen Bucht sowie Prozeßstudien zum Verhalten von Spurenmetallen beim Übergang Atmosphäre/Meerwasser. Ph.D. thesis, University of Hamburg, 236 pp.

  • Kümmerer, K.;E. Helmers (1997): Hospital effluents as a source for Pt in the environment. Sci. Tot. Environ. 193, 179–184

    Article  Google Scholar 

  • Kümmerer K.; E. Helmers, P. Hubner, G. Mascart, M. Milandri, F. Reinthaler, M. Zwakenberg (1998): European hospitals as a source for Pt in the environment: emissions with effluents — concentrations, amounts and comparison with other sources. Sci. Tot. Environ., in press

  • Laschka, D. (1996): Untersuchungen zur ökotoxikologischen Relevanz von Pt in aquatischen Systemen. Bavarian Institute for Water Research, Munich, 54 pp.

    Google Scholar 

  • Laschka, D.;T. Striebel, J. Daub, M. Nachtwey (1996): Platin im Regenabfluß einer Straße. UWSF — Z. Umweltchem. Ökotox. 8 (3), 124–129

    Article  Google Scholar 

  • Laschka, D.;M. Nachtwey (1997): Pt in municipal sewage treatment plants. Chemosphere 34 (8), 1803–1812

    Article  CAS  Google Scholar 

  • Lustig, S.;R. Schierl, F. Alt, E. Helmers, K. Kümmerer (1997). Platin: Deposition, Verteilung sowie Bedeutung für den Menschen und sein Nahrungsnetz. UWSF — Z. Umweltchem. Ökotox. 9 (3), 149–152

    Article  CAS  Google Scholar 

  • OECD (1993): Risk reduction monograph No. 1. Lead — background and national experience with reducing risk. Environment Monograph No. 65, Paris, 277 pp.

  • Prospero, J.M. (1990): Mineral-aerosol transport to the North Atlantic and North Pacific: the impact of African and Asian sources. In: The Long-range Atmospheric Transport of Natural and Contaminant Substances (Ed.A.H. Knap), Kluwer publ., Dordrecht, 59–86

    Google Scholar 

  • Puchelt, H.; U. Kramar, G.L. Cumming, D. Kristic, T. Nöltner, M. Schöttle, V. Schweike (1993): Anthropogenic Pb contamination of soils, southwest Germany. Applied Geochem. Suppl. Issue No. 2, 71–73

  • Rädlein, N.;K. G. Heumann (1995): Size fractionated impactor sampling of aerosol particles over the Atlantic Ocean from Europe to Antarctica as a methodology for source identification of Cd, Pb, Tl, Ni, Cr, and Fe. Fres. J. Anal. Chem. 352, 748–755

    Article  Google Scholar 

  • Renberg, I.;M.W. Persson, O. Emteryd (1994): Pre-industrial atmospheric Pb contamination detected in Swedish lake sediments. Nature 368, 323–326

    Article  CAS  Google Scholar 

  • Schierl, R.;G. Fruhmann (1996): Airborne Pt concentrations in Munich city buses. Sci. Tot. Environ. 182, 21–23

    Article  CAS  Google Scholar 

  • Schüürmann, G.:K.-D. Wenzel, L. Weißflog, K. Wienhold, E. Müller (1994): Ökotoxikologische Charakterisierung der Schwermetall-Immissionsmuster. UWSF — Z. Umweltchem. Ökotox. 6(5), 265–270

    Article  Google Scholar 

  • Ulrich, B. (1984): Deposition von Säure und Schwermetallen aus Luftverunreinigungen und ihre Auswirkungen in Waldökosystemen. In: Metalle in der Umwelt (Ed.E. Merian), VCH publ., Weinheim, 162–170

    Google Scholar 

  • UBA (1994): Daten zur Umwelt (Ed.: Umweltbundesamt). E. Schmidt publ., Berlin, 688 pp.

    Google Scholar 

  • Wedepohl, K. H. (1995): The composition of the continental crust. Geochim. Cosmochim. Acta 59 (7), 1217–1232

    Article  CAS  Google Scholar 

  • Zereini, E.;F. Alt, K. Rankenburg, J.-M. Beyer, S. Artelt (1997): Verteilung von PGE in den Umweltkompartimenten Boden, Schlamm, Straßenstaub, Straßenkehrgut und Wasser. UWSF — Z. Umweltchem. Ökotox. 9 (4), 193–200

    Article  CAS  Google Scholar 

  • Zereini F.;F. Dirksen, B. Skerstupp, H. Urban (1998): Sources of anthropogenic PGE: automotive catalysts versus PGE-processing industries. ESPR — Environ. Sci. Poll. Res. 5 (4) 223–230

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. FH Trier, University of Applied Sciences, environmental campus Birkenfeld, P.O. Box 30 13 80, D-55761, Birkenfeld, Germany

    Eckard Helmers

  2. Institute of Environmental Medicine and Hospital Epidemiology, University of Freiburg, Hugstetterstr. 55, D-79016, Freiburg, Germany

    Klaus Kümmerer

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  1. Eckard Helmers
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  2. Klaus Kümmerer
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An erratum to this article is available at http://dx.doi.org/10.1007/BF03039215.

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Helmers, E., Kümmerer, K. Anthropogenic platinum fluxes: Quantification of sources and sinks, and outlook. Environ. Sci. & Pollut. Res 6, 29–36 (1999). https://doi.org/10.1007/BF02987118

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  • DOI: https://doi.org/10.1007/BF02987118

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