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Table 2 Half-livesa (DT50) of pelargonic acid in subsoils from railway tracks and agricultural topsoils

From: Degradation and sorption of the herbicide pelargonic acid in subsoils below railway tracks compared to a range of topsoils

Starting concentration

5 mg/kg

15 mg/kg

water content

[% WHC]

DT50

[h]

95% CIb

water content

[% WHC]

DT50

[h]

95% CIb

Subsoils from railway tracks

Lanzenhäusern

62

2.3

(2.0–2.8)

54

10.5

(8.7–13.2)

Nottwil

48

0.99

(0.76–1.41)

44

3.7

(2.7–5.7)

Wabern

67

2.0

(1.4–3.4)

51

4.9

(4.1–6.2)

Geom. mean for railway soils

 

1.7

  

5.8

(0.24 d)

 

Agricultural topsoils

Brislach

60

0.15

(0.11–0.24)

38

1.2

(1.1–1.4)

Möhlin

72

0.16

(0.15–0.17)

49

1.8

(1.4–2.7)

Sargans

58

0.20

(0.18–0.23)

49

1.3

(1.0–1.6)

Zuzwil

58

0.17

(0.15–0.20)

37

1.5

(1.2–1.9)

Geom. mean for agricultural soils

 

0.17

  

1.4

 

DT50 value used for exposure modelling in the EU: range 0.70–1.58 days (n = 4) c

29.3

(1.22 d)

 
  1. aAll determined assuming exponential decline (SFO fit); additional data, also for “hockey-stick” fits, see additional file (chapter 1)
  2. b95% confidence interval
  3. cRef. [14]